Visualization of ion transport in Nafion using electrochemical strain microscopy.
نویسندگان
چکیده
The electromechanical response of a Nafion membrane immersed in water was probed using electrochemical strain microscopy (ESM) to redistribute protons and measure the resulting local strain that is caused by the movement of protons. We also measured the relaxation of protons from the surface resulting from proton diffusion. Using this technique, we can visualize and analyze the local strain change resulting from the redistribution and relaxation of hydrated protons.
منابع مشابه
Investigation of the connectivity of hydrophilic domains in Nafion using electrochemical pore-directed nanolithography.
A method of determining the connectivity of ion-conducting hydrophilic channels within the Nafion polymer electrolyte membrane by way of pore-directed nanolithography has been developed. Electrochemical etching of a silicon surface is performed through a Nafion-membrane mask. The resulting silicon surface imaged by tapping-mode atomic force microscopy (TMAFM) provides a footprint of the hydroph...
متن کاملSynthesis, Characterization and Transport Properties of Novel Ion-exchange Nanocomposite Membrane Containing In-situ Formed ZnO Nanoparticles
A new type of cation-exchange nanocomposite membranes was prepared by in-situ formation of ZnO nanoparticles in a blend containing sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) and sulfonated polyvinylchloride via a simple one-step chemical method. As-synthesized nanocomposite membranes were characterized using Fourier transform infrared spectroscopy, scan...
متن کاملCation Exchange Nanocomposite Membrane Containing Mg(OH)2 Nanoparticles: Characterization and Transport Properties
In this study, ion exchange nanocomposite membranes was prepared by addition of Mg(OH)2 nanoparticles to a blend containing sulfonated polyphenylene oxide and sulfonated polyvinylchloride via a simple casting method. Magnesium hydroxide nanoparticles were synthesized via a facile sono-chemical reaction and were selected as filler additive in fabrication of ion exchange nanocomposite membranes. ...
متن کاملNMR and Electrochemical Investigation of the Transport Properties of Methanol and Water in Nafion and Clay-Nanocomposites Membranes for DMFCs
Water and methanol transport behavior, solvents adsorption and electrochemical properties of filler-free Nafion and nanocomposites based on two smectite clays, were investigated using impedance spectroscopy, DMFC tests and NMR methods, including spin-lattice relaxation and pulsed-gradient spin-echo (PGSE) diffusion under variable temperature conditions. Synthetic (Laponite) and natural (Swy-2) ...
متن کاملIn situ visualization of Li-ion intercalation and formation of the solid electrolyte interphase on TiO2 based paste electrodes using scanning electrochemical microscopy.
Scanning electrochemical microscopy (SECM) inside a glove box was used for the in situ visualization of solid electrolyte interphase (SEI) formation as well as Li-ion intercalation and de-intercalation on anatase TiO2 based paste electrodes.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Chemical communications
دوره 52 4 شماره
صفحات -
تاریخ انتشار 2016